Consider the following example:
Code
\documentclass{article}
\usepackage{siunitx}
\usepackage{booktabs,dcolumn,array}
\begin{document}
\begin{table}
\centering
\begin{tabular}{l !{\quad} c c D{.}{.}{2.2} !{\quad} c c D{.}{.}{2.2}}
\toprule
\multicolumn{1}{c!{\quad}}{Times} & \multicolumn{3}{c!{\quad}}{RAAN} & \multicolumn{3}{c}{Dec}\\
\midrule
& \si{\hour} & \si{\minute} & \si{\s} & \ensuremath{^\circ} & \ensuremath{\prime} & \ensuremath{\prime\prime} \\
\midrule
11{:}40{:}28 & 00 & 03 & 45.48 & 18 & 40 & 03.78 \\
\bottomrule
\end{tabular}
\end{table}
\end{document}
Why are s not centered above 45.48 and \prime\prime not centered above 03.78 and how do I achieve this?



siunitx'S-columns and maybe\sisetup{table-parse-only}. BTW: there's also\si{\arcminute}and\si{\arcsecond}. – cgnieder Mar 6 at 22:41S-columns in this case, since I am not exactly sure how to use it? (My tries give a wrong alignment.) – Svend Tveskæg Mar 6 at 22:59