There are many ways in which you can produce tabular material; the basic options are the tabbing environment, the tabular environment, and the arrray environment; depending in your intent, you can choose which one to use. Here's a little example:
\documentclass{article}
\begin{document}
\begin{tabbing}
X \= a \= b \= c \\
\> d \> e \> f
\end{tabbing}
\begin{tabular}{cccc}
X: & a & b & c \\
& d & e & f
\end{tabular}
\[
\begin{array}{cccc}
X: & a & b & c \\
& d & e & f
\end{array}
\]
\end{document}
The above options are explained in any basic LaTeX manual.