When I use mathpazo and siunitx (version 2.3h) together, if I use \pi inside the numerical argument to \SI, it will show up in the output as "ß".
\documentclass{article}
\usepackage{mathpazo, siunitx}
\begin{document}
$\pi + \SI{\pi}{\ohm}$
\end{document}
Produces:

But when I don't use mathpazo:

Why does this happen and how can I fix it?

