Since the other cases questions ask some specific questions about it, here's a working example:
\documentclass{article}
\usepackage{amsmath}
\begin{document}
\[
g(n) =
\begin{cases}
\frac{2}{3}n & \text{wenn } n \equiv 0 \mod 3,\\
\frac{4}{3}n + \frac{1}{3} & \text{wenn } n \equiv 1 \mod 3,\\
\frac{4}{3}n - \frac{1}{3} & \text{wenn } n \equiv 2 \mod 3.
\end{cases}
\]
\end{document}
The mathmode documentation is extremely helpful for answering these sorts of questions. You can find it on your system using texdoc or its equivalent.
casesenvironment. searchcasesfirst. – Leo Liu Nov 20 '11 at 17:32