I have found this symbol defined as:
\def\ci{\perp\!\!\!\perp}
on the wikipedia page for Conditional Independence. There's this from the Comprehensive LaTex Symbol List page 106:
Donald Arseneau posted the following \mathpalette-based definition of a probabilistic-independence symbol ⊥⊥ to comp.text.tex in June 2000:
\newcommand\independent{\protect\mathpalette{\protect\independenT}{\perp}}
\def\independenT#1#2{\mathrel{\rlap{$#1#2$}\mkern2mu{#1#2}}}
The \independent macro uses \mathpalette to pass the \independenT helper
macro both the current math style and the \perp symbol. \independenT
typesets \perp in the current math style, moves two math units to the
right, and finally typesets a second—overlapping—copy of \perp, again
in the current math style. \rlap, which enables text overlap, is described
later on this page.
Frankly, I like the first version better, even though it doesn't typeset properly on my machine.
Are there any better alternatives?