I have the following table in my document, and it seems to be OK except that the topmost columns' text is not centered. I can't figure out why not. I could manually adjust the multicolumn m sizes to get there, but that does not seem like the right solution.
I have a similar table in my document and the centering works fine. This is all within a 2 column IEEE-type document. I thought maybe my table was too wide and something weird was happening - but making the table less wide does not solve the problem (although it does make the text off center in different ways). My entire table is centered on the page; I tried taking that out and leaving it left justified and that had no effect.

The TeX that generates this table is:
\begin{table*}
\centering
\caption{Results on Xilinx Virtex 5 Devices}
\label{tab:XilinxResults}
\begin{tabular}{|m{3cm}|m{1.50cm}|m{1.50cm}|m{1.30cm}|m{1.30cm}|m{1.30cm}|m{1.30cm}|m{1.30cm}|m{1.30cm}|}
\cline{2-9}
\multicolumn{1}{>{\centering}m{3.0cm}|}{ } & % blank box
\multicolumn{2}{>{\centering}m{3.0cm}|}{\bfseries Clock Frequency (MHz)} &
\multicolumn{2}{>{\centering}m{2.6cm}|}{\bfseries Throughput (Mbit/s)} &
\multicolumn{2}{>{\centering}m{2.6cm}|}{\bfseries Area (CLB Slices)} &
\multicolumn{2}{>{\centering}m{2.6cm}|}{\bfseries Throughput / Area} \tabularnewline \hline
\multicolumn{1}{|>{\centering}m{3cm}|}{\bfseries Architecture} &
\multicolumn{1}{>{\centering}m{1.50cm}|}{\bfseries 512-bit} &
\multicolumn{1}{>{\centering}m{1.50cm}|}{\bfseries 256-bit} &
\multicolumn{1}{>{\centering}m{1.30cm}|}{\bfseries 512-bit} &
\multicolumn{1}{>{\centering}m{1.30cm}|}{\bfseries 256-bit} &
\multicolumn{1}{>{\centering}m{1.30cm}|}{\bfseries 512-bit} &
\multicolumn{1}{>{\centering}m{1.30cm}|}{\bfseries 256-bit} &
\multicolumn{1}{>{\centering}m{1.30cm}|}{\bfseries 512-bit} &
\multicolumn{1}{>{\centering}m{1.30cm}|}{\bfseries 256-bit}
\tabularnewline\hline\hline
\bfseries BMW x1 &
\raggedleft 4.89 & \raggedleft 8.14 & \raggedleft 5004 & \raggedleft 4168 &
\raggedleft 12039 & \raggedleft 6164 & \raggedleft 0.42 & \raggedleft 0.68 \tabularnewline \hline
\bfseries BMW x1-PPL18 &
\raggedleft 46.51 & \raggedleft 70.97 & \raggedleft 47628 & \raggedleft 36335 &
\raggedleft 24564 & \raggedleft 11610 & \raggedleft 1.84 & \raggedleft 2.96 \tabularnewline \hline
\bfseries BMW /32(h) &
\raggedleft 44.27 & \raggedleft 69.41 & \raggedleft 1416 & \raggedleft 1110 &
\raggedleft 4001 & \raggedleft 2211 & \raggedleft 0.35 & \raggedleft 0.50 \tabularnewline \hline
\bfseries CubeHash x1 &
\raggedleft 152.70 & \raggedleft 151.93 & \raggedleft 2443 & \raggedleft 2430 &
\raggedleft 745 & \raggedleft 672 & \raggedleft 3.28 & \raggedleft 3.62 \tabularnewline \hline
\bfseries CubeHash x1-PAR5 &
\raggedleft 151.26 & \raggedleft 151.56 & \raggedleft 12101 & \raggedleft 12125 &
\raggedleft 3742 & \raggedleft 3490 & \raggedleft 3.23 & \raggedleft 3.47 \tabularnewline \hline
\bfseries CubeHash x1-PAR17 &
\raggedleft N/A & \raggedleft 150.49 & \raggedleft N/A & \raggedleft 40933 &
\raggedleft N/A & \raggedleft 11360 & \raggedleft N/A & \raggedleft 1.91 \tabularnewline \hline
\bfseries CubeHash x1-PAR33 &
\raggedleft 150.65 & \raggedleft N/A & \raggedleft 79542 & \raggedleft N/A &
\raggedleft 24570 & \raggedleft N/A & \raggedleft 3.24 & \raggedleft N/A \tabularnewline \hline
\bfseries CubeHash /2(h) &
\raggedleft 173.52 & \raggedleft 184.71 & \raggedleft 1388 & \raggedleft 1477 &
\raggedleft 733 & \raggedleft 624 & \raggedleft 1.89 & \raggedleft 2.37 \tabularnewline \hline
\end{tabular}
\end{table*}

\documentclassand the appropriate packages so that those trying to help don't have to recreate it. Your is not quite minimal. For example, can you reproduce the problem if you remove all the rows except one? Same for columns... – Peter Grill Mar 7 '12 at 5:14\multicolumn{2}{>{\centering}m{3.0cm}|}{\bfseries Clock Frequency (MHz)}. The width is already defined above. I think you can simply put\multicolumn{2}{c|}{\bfseries Clock Frequency (MHz)}. What about adding\arraybackslashafter\centering. If you provide a MWE as werner said it would be better. – Harish Kumar Mar 7 '12 at 5:30