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I have this MWE:

            \multicolumn{2}{|c|}{\textbf{SED}} & \multirow{2}{*}{\textbf{\% compressione}} \\
            \textbf{MC} & \textbf{DP} & \\ 
            0.00016032 & 0.0001750267 & 10\%\\

It realizes this image: enter image description here The first two columns are correctly formatted to the left, but I want that just MC and DP will be centered, how can I do that?

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I suggest you read the documentation of the package booktabs, see CTAN: tug.ctan.org/pkg/booktabs –  Sveinung May 8 '12 at 17:42
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Like you did it with the "SED": with \multicolumn:

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