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How could I add a note ... or a footnote at the beginning of the Table of Contents, something like 'Chapters with * can be skipped on a first reading'...?

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You can use \addtocontents to add whatever you like (*) to the .toc file that is later read in by \tableofcontents. (*) With the caveat that you adequately \protect any fragile commands you might wish to include.

Something like this might work for you:


\chapter[Two (*)]{Two}
\addtocontents{toc}{\bigskip\noindent Note: chapters with * can be skipped on a first reading.}

The .toc file it produces looks like this:

\contentsline {chapter}{\numberline {1}One}{1}{chapter.1}
\contentsline {chapter}{\numberline {2}Two (*)}{4}{chapter.2}
\contentsline {chapter}{\numberline {3}Three}{7}{chapter.3}
\vspace \bigskipamount \noindent Note: chapters with * can be skipped on a first reading.

which eventually leads to output that looks like this:

alt text

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