According to the pdfx documentation it should be possible to add a Subject field to the XMP metadata file. Addition of this field however seems to cause an unexpected error during compilation of the LaTeX source into a PDF/A-1b file (pdfLaTex).
Try to compile the following source:
\documentclass[a4paper, 12pt]{article}
\usepackage[a-1b]{pdfx}
\begin{document}
Hello, World!
\end{document}
using this metadata:
\Author{Me}
\Title{Hello, World!}
\Subject{Hello, World! example.}
\Org{Me}
\Keywords{Hello\sep World}
The source compiles without errors after omission of the Subject tag.
Thanks.