Here is an MWE:
\documentclass[a4paper,11pt]{article}
\usepackage{soul}
\usepackage{amsmath}
\usepackage{amssymb}
\usepackage{longtable}
\usepackage{booktabs}
\usepackage{multirow}
\usepackage{fontspec}
\setmainfont{Arial}
\usepackage{hyperref}
\begin{document}
\begin{longtable}{@{}rrrrrrr@{}} \toprule
\multicolumn{7}{c}{Vertical} \\
$i$
& \multicolumn{2}{c}{$\langle x^1_{i}, y^1_{i} \rangle$}
& \multicolumn{2}{c}{$\langle x^2_{i}, y^2_{i} \rangle$}
& $\measuredangle_{i}$ & $m_{i}$ \endhead \midrule
$1$
& $\langle 17.90,$ & $27.19 \rangle$
& $\langle -192.10,$ & $69.53 \rangle$
& $-90.0°$
& $29$ \\
$2$
& $\langle 47.65,$ & $31.32 \rangle$
& $\langle -162.35,$ & $73.66 \rangle$
& $-90.0°$
& $21$ \\
$3$
& $\langle 85.94,$ & $32.43 \rangle$
& $\langle -124.06,$ & $74.77 \rangle$
& $-90.0°$
& $27$ \\
$4$
& $\langle 117.53,$ & $34.29 \rangle$
& $\langle -92.47,$ & $76.63 \rangle$
& $-90.0°$
& $23$ \\
$5$
& $\langle 154.71,$ & $29.83 \rangle$
& $\langle -55.29,$ & $72.17 \rangle$
& $-90.0°$
& $21$ \\
\addlinespace
\multicolumn{3}{l}{Average}
& \multicolumn{4}{r}{$\tilde{m} = \frac{1}{n}\sum_{i=1}^{n}m_{i}$} = $24.0$ \\ \bottomrule
\end{longtable}
\end{document}
Result:

The obvious problem is that header columns are misaligned. $i$ should be above the numbers (first column) and $m_i$ should be above the last column.
longtablecan be typeset with the correct lengths. As an aside: I'd put the first\midrulebefore\endhead(with\\in front of it). – egreg Sep 29 '12 at 22:10{@{}rr@{${},{}$}rr@{${},{}$}rrr@{}}as column specification and remove the commas in the table body. – Qrrbrbirlbel Sep 29 '12 at 22:18longtableis not yet stable. Don't worry too much: during document preparation, you run frequently LaTeX, so this is a minor problem. – egreg Sep 29 '12 at 22:27