Math fonts do not make ff into a ligature the way text fonts do as it may sometimes obscure the meaning of two separate identifiers juxtaposed,

$\tau_{ff}$ $\tau_{f\!f}$ $\tau_{\mathit{ff}}$
If the meaning of your subscript is some kind of invisible product of two f then use one of the first two, or some other negative space other than \! to taste. If on the other hand it is a multi-letter identifier with name ff then it is more appropriate to use a text font, as in the third example where the text italic font is used in math mode via \mathit and there ff produces a single ff ligature glyph.
$\tau_{\mathrm{ff}}$– egreg Sep 30 '12 at 20:34$\tau_fand$\tau_{ff}, where both are abbreviations - (ff is a special kind of f). Would you then propose to set the single f upright as well? – Joma Sep 30 '12 at 20:52