\documentclass{scrbook}
\begin{document}
\tableofcontents
\addcontentsline{toc}{section}{Introduction} % what looks better section or chapter?
\section*{Introduction} % * prevents the numbering. We already added it manually to toc above
\chapter{Theory}
\chapter{Experiment}
\end{document}

thanks to the comment I found a better solution in the book 2:
use one of the commands
\addpart[short]{long headline}
\addpart*{long headline}
\addchap[short]{long headline}
\addchap*{long headline}
\addsec[short]{long headline}
\addsec*{long headline}
Working example
\documentclass{scrbook}
\begin{document}
\tableofcontents
\addpart[Day 1]{Day one}
\addsec*{Introduction}
\addchap{Theory}
\addpart[Experiments]{Nice experiments}
\end{document}
Page 115 in Kohm, Markus und Morawski, Jens-Uwe:
KOMA-Script - Die Anleitung;
DANTE e.V., Lehmanns Media, 4., erweiterte Aufl. 2012
592 Seiten
(ISBN 978-3-86541-459-5;
\addcontentsline{toc}{<level>}{<text>}where<level>ispart,chapter, … and<text>could beIntro. (Or just plain\chapter{Intro}?) This could also be something for anabstractenvironment or macro. – Qrrbrbirlbel Nov 17 '12 at 16:02