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A “real” math font, such as those that can be used with unicode-math, has glyphs specially tailored for math fonts. For instance with \documentclass{article} \usepackage{unicode-math} \setmainfont{Latin Modern Roman} \setmathfont{Latin Modern Math} \begin{document} \textit{f} $f(x)$ \end{document} the character used for the second “f” is U+1D453 ...


As you have a variable font for the 'unit' part of quantities, and that is a text mode font, I think you are best off using text mode with siunitx \sisetup{unit-mode = text} This will then use whatever the current text font is for units, so the math font will have no impact. (Untested as I don't have the appropriate fonts.)

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