Do you mean something like this?
\documentclass{article}
\usepackage{filecontents}
\begin{filecontents}{\jobname.bib}
@article{someguykey2010,
author="SomeGuy",
title="A journal article",
year=2010,
journal="A Journal",
}
@article{someotherguykey2013,
author="SomeOtherGuy",
title="A journal article",
year=2013,
journal="A Journal",
}
\end{filecontents}
\usepackage[round]{natbib}
\begin{document}
``some guy said this'' \citep[as cited in \citealp{someotherguykey2013}]{someguykey2010}
\bibliographystyle{plainnat}
\bibliography{\jobname}
\end{document}
If you want, you can even define a new command \doublecitep
\newcommand{\doublecitep}[2]{\citep[as cited in \citealp{#2}]{#1}}
and use it like
\doublecitep{someguykey2010}{someotherguykey2013}
instead of
\citep[as cited in \citealp{someotherguykey2013}]{someguykey2010}