\begin{table}[htbp]
\centering
\caption{Zusammensetzung der Proben}
\begin{tabular}{cccc}
\toprule
\multirow{2}{*}{Probe} & [TRA-Puffer 2.5$\frac{\text{mg}}{\text{ml}}$ Lipase] & [Gummi-Arabicum-Lösung] & [Speiseöl]\\
& = \si{\ml} & = \si{\ml} & = \si{\ml} \\
\midrule
1 & 5 & 20 & 0.03 \\
\bottomrule
\end{tabular}%
\label{tab:Zusammensetzung}%
\end{table}%
this renders just fine
\begin{table}[htbp]
\centering
\caption{Zusammensetzung der Proben}
\begin{tabular}{ccc}
\toprule
[TRA-Puffer 2.5$\frac{\text{mg}}{\text{ml}}$ Lipase] & [Gummi-Arabicum-Lösung] & [Speiseöl]\\
= \si{\ml} & = \si{\ml} & = \si{\ml} \\
\midrule
5 & 20 & 0.03 \\
\bottomrule
\end{tabular}%
\label{tab:Zusammensetzung}%
\end{table}%
with this code I'm stuck at rendering the .tex that contains this table. Any ideas why?