I guess your document is oneside
? Then you can use
\documentclass[oneside]{scrbook}
\usepackage[headsepline,footsepline,manualmark]{scrlayer-scrpage}
\clearpairofpagestyles
\ihead{TEMA 13}
\chead{Polinomios}
\ohead{\pagemark}
\ofoot{Oposiciones}
\cfoot[\pagemark]{}
\addtokomafont{pageheadfoot}{\upshape}
\usepackage{blindtext}% dummy text
\begin{document}
\blinddocument
\end{document}
If your document is twoside
there are two cases:
TEMA 13 should be on the left hand side on even pages and on the right hand side on odd pages? Then you can use the same code as for the oneside
option because the i
in \ohead
means "inner".
TEMA 13 should be on the right hand side on both the even and the odd pages? Then you have to use \lehead
and \lohead
(le
means left even, lo
left odd).
Code for the second case:
\documentclass{scrbook}
\usepackage[headsepline,footsepline,manualmark]{scrlayer-scrpage}
\clearpairofpagestyles
\lehead{TEMA 13}\lohead{TEMA 13}
\chead{Polinomios}
\rehead{\pagemark}\rohead{\pagemark}
\lefoot{Oposiciones}\lofoot{Oposiciones}
\cfoot[\pagemark]{}
\addtokomafont{pageheadfoot}{\upshape}
\usepackage{blindtext}% dummy text
\begin{document}
\blinddocument
\end{document}