The problem is that a tabular
where vertical rules are used must have all cells specified, either empty or not.
Your “skipped rows” are obtained by \\ \\
, which just specifies the first cell in the row as empty. With \\ & \\
also the second cell is specified. The code
\begin{tabular}{|c|c|}
\hline
Rango de Tiempo $[s]$ & Viscosidad $[\frac{cm^{2}}{s}]$\\ \hline
\multirow{2}{*}{$34 - 115$} & \multirow{2}{*}{$0,224t + \frac{185}{t}$ }\\ & \\ \hline
\multirow{2}{*}{$115 - 215$} & \multirow{2}{*}{$0,223t + 1,55$} \\ & \\
\hline
\multirow{2}{*}{> 215} & \multirow{2}{*}{$0,224t + \frac{185}{t}$ } \\ & \\ \hline
\end{tabular}
will produce

that, however, has several small mistakes in it.
Symbols for units should be upright and in parentheses, not square brackets that denote dimensions, rather than units (use in Spanish might be different, though).
The decimal comma should not be spaced; with \usepackage[spanish]{babel}
, the default output of $0.224$
would be 0,224 with no space.
You shouldn't use a minus sign for the interval, but an en-dash.
Here are fixes for these issues.
\documentclass{article}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage[spanish]{babel}
\usepackage{bigstrut,array}
\begin{document}
\begin{table}[htbp]
\centering
\setlength{\bigstrutjot}{6pt}
\begin{tabular}{|c<{\bigstrut}|c|}
\hline
Rango de Tiempo (s) & Viscosidad (cm$^{2}$/s) \\
\hline
$34$--$115$ & $0.224t + \frac{185}{t}$ \\
\hline
$115$--$215$ & $0.223t + 1.55$ \\
\hline
$>215$ & $0.224t + \frac{185}{t}$ \\
\hline
\end{tabular}
\end{table}
\end{document}

Finally, using siunitx
is better (and also booktabs
); it's necessary to disable the “quoting” mechanism of babel-spanish
that goes into the way also in several other circumstances.
\documentclass{article}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage[spanish,es-noquoting]{babel}
\usepackage{booktabs,siunitx}
\sisetup{range-phrase=--,output-decimal-marker={,}}
\begin{document}
\begin{table}[htbp]
\centering
\begin{tabular}{cc}
\toprule
Rango de Tiempo (\si{s}) & Viscosidad (\si{cm^2/s}) \\
\midrule
\numrange{34}{115} & $\num{0.224}t + \frac{\num{185}}{t}$ \\
\addlinespace
\numrange{115}{215} & $\num{0.223}t + \num{1.55}$ \\
\addlinespace
\num{> 215} & $\num{0.224}t + \frac{\num{185}}{t}$ \\
\bottomrule
\end{tabular}
\end{table}
\end{document}

\multirow
here as all the cells in a row are supposed to be the same height. So just get rid of the\multirow
s as they are being misused and abused and aren't needed. (They are misused because if you use\multirow{2}...
, then you need to leave the relevant gap in the next row of the table, which you never do. – cfr Apr 2 '16 at 2:23