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This question already has an answer here:

I am writing an article. I would like the references to appear in the order in which they occur in the paper. I am using natbib, but can't seem to figure out how to do it.

marked as duplicate by Mico, Mensch, Zarko, Werner, barbara beeton Jul 6 '16 at 21:07

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    Welcome to TeX.SE! As you're using the natbib citation management package, you should probably use the unsrtnat bibliography style. Simply issue the instruction \bibliographystyle{unsrtnat} somewhere in the document and then run LaTeX, BibTeX, and LaTeX twice more to fully propagate the changes. – Mico Jul 6 '16 at 19:25
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