The object that (potentially) has to be resized via \adjustbox
is the tabular
material, not the table
environment.
Also, as @egreg has already pointed out in a comment, don't use vertical rules if you use the line-drawing macros of the booktabs
package. Actually, coming to think of it, don't use vertical rules at all, whether or not you use the line-drawing macros of the booktabs
package...

\documentclass[portuguese]{article} % or spanish?!
\usepackage{lmodern,babel,adjustbox,booktabs,multirow}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\begin{document}
\begin{table}[!htbp]
\adjustbox{max width=\textwidth}{%
\centering
\begin{tabular}{@{}l*{6}{c}@{}}
\toprule
\multicolumn{1}{c}{\multirow{2}{*}{\textbf{Sub-Item}}} &
\multirow{2}{*}{\textbf{Projeto}} &
\multirow{2}{*}{\textbf{Processos}} &
\multicolumn{2}{c}{\textbf{Valor individual por}} &
\multirow{2}{*}{\textbf{Quantidade}} &
\multirow{2}{*}{\textbf{Total}} \\ \cmidrule(lr){4-5}
& & & \textbf{Projeto} & \textbf{Processo} \\
\midrule
Serviço de medição & 1 & 4 & & & 2 & \\ %%\midrule
Serviço de apoio a projeto & 1 & 4 & & & 1 & \\
\midrule
\multicolumn{6}{r}{\textbf{Valor total}} & \\
\bottomrule
\end{tabular}}
\caption{Proposta de preço para item 1}
\label{PropostaItem1}
\end{table}
\end{document}
Addendum with two alternative specifications of some or all of the tabular material:
If you're looking to give your table an cleaner and simpler, i.e., less turgid, look, don't use bold. I strongly suggest you (a) get rid of the bold font weights in the header cells and (b) dispense with the \multirow
directives as well.
Using \adjustbox
to make the tabular
-like material fit inside the width of the textblock "works", but only in an extremely narrow sense. What's wrong with the \adjustbox
approach, from a typographic experience? Most importantly, you run the serious risk of reducing the font size so much as to make the table well-nigh illegible. Thus, instead of taking the mechanical approach, think about (a) using automatic line breaks and text wrapping in some of the columns, (b) reducing the amount of intercolumn whitespace, and (c) shortening the labels used in the header row. The second table below implements all three ideas. I hope you will agree that the result is far more readable than the compressed table above it is.

\documentclass[portuguese]{article}
\usepackage{lmodern,babel,adjustbox,booktabs,
tabularx,ragged2e,xcolor}
\newcolumntype{L}{>{\RaggedRight\hangindent=1em \hangafter=1 \arraybackslash}X}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\begin{document}
\begin{table}[!htbp]
\textcolor{red}{A\@. tabular environment, compressed}
\adjustbox{max width=\textwidth}{%
\begin{tabular}{@{}l*{6}{c}@{}}
\toprule
Sub-Item & Projeto & Processos & \multicolumn{2}{c}{Valor individual por} & Quantidade & Total \\
\cmidrule(lr){4-5}
& & & Projeto & Processo \\
\midrule
Serviço de medição & 1 & 4 & & & 2 & \\ %%\midrule
Serviço de apoio a projeto & 1 & 4 & & & 1 & \\
\midrule
\multicolumn{6}{r}{Valor total} & \\
\bottomrule
\end{tabular}}
\bigskip
\textcolor{red}{B\@. tabularx environment, uncompressed}
\setlength\tabcolsep{3pt} % default is 6pt
\begin{tabularx}{\textwidth}{@{}L*{6}{c}@{}}
\toprule
Sub-Item & Projeto & Processos & \multicolumn{2}{c}{Valor individual por} & Quant. & Total \\
\cmidrule(lr){4-5}
& & & Projeto & Processo \\
\midrule
Serviço de medição & 1 & 4 & & & 2 & \\ %%\midrule
Serviço de apoio a projeto & 1 & 4 & & & 1 & \\
\midrule
\multicolumn{6}{r}{Valor total} & \\
\bottomrule
\end{tabularx}
\end{table}
\end{document}
\adjustbox
has to be thetabular
environment, not thetable
environment.booktabs
rules (\toprule
,\midrule
and\bottomrule
).figure
inside aminipage
?\small
if the text needs to be smaller.