Using this code, I am facing the problem shown in the right side of the picture. The Equation spans beyond the page margin on the right.
\documentclass[aps,prl,reprint]{revtex4-1}
\usepackage{blindtext}
\usepackage{graphicx}
\usepackage{graphics}
\usepackage{bm} % for math
\usepackage{verbatim} % for math
\usepackage{amsfonts}
\usepackage{amsmath}
\usepackage{bm}
\usepackage{amssymb}
\usepackage{adjustbox}
\DeclareMathOperator{\RE}{Re}
\DeclareMathOperator{\IM}{Im}
\newcommand{\revtex}{REV\TeX\ }
\newcommand{\classoption}[1]{\texttt{#1}}
\newcommand{\macro}[1]{\texttt{\textbackslash#1}}
\newcommand{\m}[1]{\macro{#1}}
\newcommand{\env}[1]{\texttt{#1}}
\setlength{\textheight}{9.5in}
\newenvironment{psmallmatrix}
{\left[\begin{smallmatrix}}
{\end{smallmatrix}\right]}
\begin{document}
\begin{align*}
\tiny{var(\mathbf{\theta^* - \hat{\theta^*}})} \ge
\begin{psmallmatrix}
2 & 0 & 0 & 0 & 0 \\[3ex]
0 & 2 & 0 & 0 & 0 \\[3ex]
0 & 0 & 2 & 0 & 0\\[3ex]
0 & 0 & 0 & 2 & 0 \\[3ex]
0 & 0 & 0 & 0 & 1
\end{psmallmatrix}
\begin{psmallmatrix}
\tiny{J_{11}^{-1}} & \tiny{0} & \tiny{\Delta_1^{-1}} & -\Delta_1^{-1}J_{14}{J_{24}}^{-1} & 0 \\[3ex]
0 & J_{22}^{-1} & {-J_{24}}^{-1}J_{23}\Delta_1^{-1} & {J_{24}}^{-1}+{J_{24}}^{-1}J_{23}\Delta_1^{-1}J_{14}J_{24}& 0 \\[3ex]
\Delta_2^{-1} & -\Delta_2^{-1}J_{32}J_{42}^{-1} & J_{33}^{-1} & 0 & 0\\[3ex]
\tiny{-J_{42}^{-1}J_{41}\Delta_2^{-1}} & {J_42}^{-1} + {J_42}^{-1}J_{41}\Delta_2^{-1}J_{32}{J_42}^{-1} & 0 & J_{44}^{-1} & 0 \\[3ex]
0 & 0 & 0 & 0 & 1
\end{psmallmatrix}
\end{align*}
\end{document}
I tried using the
\begin{figure*}[b]%% over both colum
\begin{align*}
\nonumber
\end{align*}
\end{figure*}
But the problem with this command is that the equation / matrix appears at the bottom of the page whereas, the text describing / referencing to this Equation is somewhere else in the document. This approach is very unappealing visually. So, is there a command so that the matrix / equation appears with the text and also fits in the page for an article in double column.
Question : How can I break the two column format in specific areas where an Equation extends beyond the page margin? I have several such large matrices in my document. I am using WinEdit7.1 Editor.
UPDATE: This is the output that I am getting based on the answer. The problem still remains as can be seen from the picture; the equation goes beyond the margin on right side.
! LaTeX Error: \begin{document} ended by \end{ducument}.