\multicolumn
also works in environment array
:
\documentclass{article}
\usepackage{amsmath}
\newcommand{\dd}{{\rm d}}
\begin{document}
\begin{equation}
\left(
\begin{array}{c c c c}
1 & 0 & \ldots & 0 \\
\dd_{1,1} & \dd_{1,2} & \ldots & \dd_{1,N} \\
\multicolumn{4}{c}{\mathcal{A}} \\
\dd_{N,1} & \dd_{N,2} & \ldots & \dd_{N,N} \\
0 & 0 & \ldots & 1
\end{array}
\right)
\end{equation}
\end{document}
Package amsmath
provides environments for matrices (with better spacing of the brackets). Additionally, a little vertical space is added on top of the line with "A", see Mico's comment.
\documentclass{article}
\usepackage{amsmath}
\newcommand{\dd}{{\rm d}}
\begin{document}
\begin{equation}
\begin{pmatrix}
1 & 0 & \ldots & 0 \\
\dd_{1,1} & \dd_{1,2} & \ldots & \dd_{1,N} \\[.5ex]
\multicolumn{4}{c}{\mathcal{A}} \\
\dd_{N,1} & \dd_{N,2} & \ldots & \dd_{N,N} \\
0 & 0 & \ldots & 1
\end{pmatrix}
\end{equation}
\end{document}