I have tried both \hline and \bottom rule, but for some reason I cannot get a bottom horizontal line on my table.
\documentclass{report}
\usepackage{amsmath}
\begin{document}
\begin{center}
\captionof{table}{Table of Legendre Polynomials\label{Tab:Tcr}}
\begin{tabular}{|l|}
\hline
\parbox{3cm}
{\begin{align*}
P_0(x) &= 1\\
P_1(x) &= x\\
P_2(x) &= \frac{1}{2} \left(3x^2 -1\right)\\
P_3(x) &= \frac{1}{2} \left(5x^3 - 3x\right)\\
P_4(x) &= \frac{1}{8} \left(35x^4 - 30x^2 + 3\right)\\
P_5(x) &= \frac{1}{8}\left(63x^5 - 70x^3 + 15x\right)\\
P_6(x) &= \frac{1}{16}\left(231x^6 - 315x^4 + 105x^2 -5\right)\\
P_7(x) &= \frac{1}{16}\left(429x^7 - 693x^5 + 315x^3 - 35x\right)\\
P_8(x) &= \frac{1}{128}\left(6435x^8 - 12012x^6 + 6930x^4 - 1260x^2 + 35\right)
\end{align*}}\\
\hline
\end{tabular}
\end{center}
\end{document}
\end{align*}}
.! Undefined control sequence. l.5 \captionof