I asked how to draw a methane with correct dashes and wedges. All was fine till I realized the plane I added should cut through the carbon atom in the middle. lt doesn't.
The solution I see is to draw the plane and then draw again half of the carbon atom. I've drawn polygons before, but drawing a dome is beyond me. I tried to imitate these questions but failed, partially because they draw the "northern" hemisphere instead of the "western".
Code
\documentclass{standalone}
\usepackage{tikz}
\usetikzlibrary{positioning,backgrounds,decorations.pathreplacing}
\usepackage{tikz-3dplot,calc}
\colorlet{hyd}{white}
\colorlet{carb}{black!55}
\colorlet{atomshell}{black}
\colorlet{colsigmaMet}{blue!70!cyan}
\colorlet{colsigmaarrowMet}{violet}
\begin{document}
\tdplotsetmaincoords{85}{125}% Determines point of view
\begin{tikzpicture}[tdplot_main_coords,
H atom/.style={circle,fill=hyd,draw=atomshell,thick,inner sep=4.5pt},
C atom/.style={circle,fill=carb,draw=atomshell,thick,inner sep=9pt}]
\def\c{1.5}
\coordinate (c01) at (0,0,0);
\coordinate (c01) at (0,0,0);
\coordinate (h01) at (\c,\c,\c);
\coordinate (h02) at (-\c,-\c,\c);
\coordinate (h03) at (\c,-\c,-\c);
\coordinate (h04) at (-\c,\c,-\c);
\coordinate (cor01) at (\c,-\c,\c);
\coordinate (cor02) at (-\c,\c,\c);
\coordinate (cor03) at (\c,\c,-\c);
\coordinate (cor04) at (-\c,-\c,-\c);
% Cube's edges
\begin{scope}[thick,line join = round]
\draw (h01) -- (cor01) -- (h02) -- (cor02) -- cycle;
\draw (h03) -- (cor04) -- (h04) -- (cor03) -- cycle;
\draw (h03) -- (cor01);
\draw (h04) -- (cor02);
\draw (h01) -- (cor03);
\end{scope}
% Solid bonds (dash and wedge not needed for this projection)
\begin{scope}[very thick]
\draw (c01) -- (h01);
\draw (c01) -- (h02);
\draw (c01) -- (h03);
\draw (c01) -- (h04);
\end{scope}
\begin{scope}[on background layer]
\begin{scope}[thick,line join = round]
\draw (h02) -- (cor04);
\end{scope}
\end{scope}
\begin{scope}[xshift = -9em, yshift = -6em]
\draw [->] (0,0,0) -- (0.9,0,0) node [below right=-0.2em and -0.2em] {$x$};
\draw [->] (0,0,0) -- (0,0.7,0) node [below left= -0.2em and -0.2em] {$y$};
\draw [->] (0,0,0) -- (0,0,0.6) node [below left] {$z$};
\end{scope}
% Carbon atom
\path (c01) node[C atom]{};
% Shaded plane
\fill[colsigmaMet,opacity=0.65] (h01) -- (h02) -- (cor04) -- (cor03) -- cycle;
\draw[->,colsigmaarrowMet,thick] (c01) -- ($0.6*(1,-1,0)$);
% H atoms
\path
foreach \X in {1,...,4} {
(h0\X) node[H atom](H0\X){} };
\node at (h01) [below right=0.15em and 0.3em] {$h_1$};
\node at (h02) [above left=0.3em and 0.3em] {$h_2$};
\node at (h03) [left=0.6em] {$h_3$};
\node at (h04) [right=0.6em] {$h_4$};
\end{tikzpicture}
\end{document}