It is not clear (to me), what you like to have in box. So, below are two options:
\documentclass[margin=3mm, preview]{standalone} % you not say, which document class you use ...
\usepackage{amsmath}
\begin{document}
\begin{equation}\label{eq:debil1}
\boxed{
\begin{split}
& \int\limits_{\Omega} \frac{1}{\mu}\nabla\times\mathbf{A}\cdot\nabla\times\mathbf{\hat{A}}d\Omega +
\int\limits_{\Omega_{b}}
\sigma\frac{\partial\mathbf{A}}{\partial t}\cdot\mathbf{\hat{A}}d\Omega_b +
\int\limits_{\Omega_{b}} \sigma\frac{\partial(\nabla V)}{\partial t} \cdot\mathbf{\hat{A}}d\Omega_b \\
& = \int\limits_{\Gamma_{b}}
\left[\frac{1}{\mu}\nabla\times\mathbf{A}\times\mathbf{n}\right]
\cdot\mathbf{\hat{A}}d\Gamma_b
\end{split}
}
\end{equation}
or
\medskip
\fbox{\begin{minipage}{\dimexpr\textwidth-2\fboxsep+2\fboxrule\relax}
\begin{equation}\label{eq:debil1}
\begin{split}
& \int\limits_{\Omega} \frac{1}{\mu}\nabla\times\mathbf{A}\cdot\nabla\times\mathbf{\hat{A}}d\Omega +
\int\limits_{\Omega_{b}}
\sigma\frac{\partial\mathbf{A}}{\partial t}\cdot\mathbf{\hat{A}}d\Omega_b +
\int\limits_{\Omega_{b}} \sigma\frac{\partial(\nabla V)}{\partial t} \cdot\mathbf{\hat{A}}d\Omega_b \\
& = \int\limits_{\Gamma_{b}}
\left[\frac{1}{\mu}\nabla\times\mathbf{A}\times\mathbf{n}\right]
\cdot\mathbf{\hat{A}}d\Gamma_b
\end{split}
\end{equation}
\end{minipage}}
\end{document}