This is just a subtle difference from the @lockstep's solution, which enables you to put subtitles on each sub-list besides the main title.
% create a list of cited and uncited refereces with biblatex
\documentclass[12pt]{article}
% biblatex
\usepackage[backend=bibtex, sorting=none, style=numeric-comp, defernumbers=true]{biblatex} % using biblatex
\addbibresource{refs.bib} % add reference file
% for each cited reference create a category named "cited"
\DeclareBibliographyCategory{cited}
\AtEveryCitekey{\addtocategory{cited}{\thefield{entrykey}}}
\begin{document}
This one is cited \cite{jiao2013characterization}.
\nocite{*}
\printbibheading
\printbibliography[category=cited,heading=subbibliography,title={Cited papers}]
\printbibliography[title={Supplementary papers},heading=subbibliography,notcategory=cited]
\end{document}
refs.bib
might be something like this
@article{jiao2013characterization,
title={Characterization of high-latitude ionospheric scintillation of GPS signals},
author={Jiao, Yu and Morton, Yu T and Taylor, Steven and Pelgrum, Wouter},
journal={Radio Science},
volume={48},
number={6},
pages={698--708},
year={2013},
publisher={AGU}
}
@article{linty2018detection,
title={Detection of GNSS ionospheric scintillations based on machine learning decision tree},
author={Linty, Nicola and Farasin, Alessandro and Favenza, Alfredo and Dovis, Fabio},
journal={IEEE Transactions on Aerospace and Electronic Systems},
volume={55},
number={1},
pages={303--317},
year={2018},
publisher={IEEE}
}