The commands \left
and \right
have to appear always in pairs within a single alignment cell. For this reason it is not possible to split them over several lines.
To achieve the desired outcome, you have two possibilities: one is to use to make artificial pairs by using an empty delimiter denoted by .
, e.g., \left( formula \right.
and on the next line \left. formula \right)
. The problem here is that you may end up with differently sized parentheses if your formulas have different heights (in your example I guess you are ok).
The alternative is to choose the delimiter size manually using \bigl
, \Bigl
, \biggl
, or \Biggl
instead of \left
and \bigr
, etc. instead of \right
.
Do not just use \bigg
without the "l" or "r" as this changes the parentheses to an ordinary symbol instead of a mathopen
or mathclose
atom and that changes the spacing!
There are a few things not quite correct in your formula:
- in
amsmath
alignment should be specified to the left of the relational symbol, i.e., &=
not =&
- I replaced most of the
\left/\right
in favor of explicit delimiters as the parentheses should not get bigger than the integrals
- On continuation lines one can use
\phantom
to move the second line inwards. This is a bit tricky and may require using \mathrel
as well to tell LaTeX that something is still a relation, but it is worth the effort in the quality of the output.
- It may be worth the time to read up a good documentation on the
amsmath
package if you typeset this kind of formulas.
- One final advice: while you can't leave empty lines in formulas there is no reason not to split it in the source over many lines as this makes understanding and editing it much easier :-)
So here is my version of your formula (not beautifully layed out on the input but perhaps a little better already):
\documentclass[a4paper,11pt]{article}
\usepackage{amsmath}
\usepackage{amssymb}
\usepackage{amsfonts}
\newcommand{\diff}{\mathop{}\!\mathrm{d}}
\begin{document}
\begin{align*}
\bullet \int\limits_V\!G(\mathbf{x,x^\prime})\rho(\mathbf{x^\prime})\;\diff^3x
&= \sum_{l=0}^{\infty}\dfrac{Q}{8\pi^2R^2(2l+1)}
\cdot \Biggl(\int\limits_{a}^{b}\!\left[r_{<}^l -
\dfrac{a^{2l+1}}{r_<^{l+1}}\right]\left[\dfrac{1}
{r_<}-\dfrac{r_<^l} {b^{2l+1}}\right]\delta(r-R)\;\diff r\Biggr)
\\
&\mathrel{\phantom{=}} % <--- this makes space of a relational =
\mathrel\cdot % <--- tricky this is no longer considered a relation because of the phantom above
\Biggl( \int\limits_{0}^{\pi}\!P_l(\cos{\theta^\prime})P_l(\cos{\theta})\cos{\theta}\;\diff
\theta\Biggr)
\cdot \underbrace{\left(\int\limits_{0}^{2\pi}\!\diff \phi\right)}_{2\pi}
\\
&= \sum_{l=0}^{\infty}\dfrac{Q}{4\pi R^2(2l+1)}\cdot
\Biggl( \int\limits_{a}^{R}\!\left[r_{<}^l-\dfrac{a^{2l+1}}{r_<^{l+1}}\right]\left[\dfrac{1}{r_<}
- \dfrac{r_<^l}{b^{2l+1}}\right]\delta(r-R)\;\diff r_<
\\
&\phantom{=\sum_{l=0}^{\infty}\dfrac{Q}{4\pi R^2(2l+1)}\cdot\Biggl(} % <--- this makes space!
+\int\limits_{R}^{b}\!\left[r_{<}^l-\dfrac{a^{2l+1}}{r_<^{l+1}}\right]\left[\dfrac{1} {r_<}
-\dfrac{r_<^l}{b^{2l+1}}\right]\delta(r-R)\;\diff r_> \Biggr)
\\
&\mathrel{\phantom{=}}
\mathrel\cdot
\Biggl(P_l(\cos{\theta^\prime})\int\limits_{0}^{\pi}P_l(\cos{\theta})\underbrace{\cos{\theta }}_{P_1}\;\diff\theta\Biggr)
\end{align*}
\end{document}
And here is the result--enjoy:

just noticed I forgot to change \left/\right
in the underbrace part ... well :-)
\left( ... \right.
to suppress one side of the delimiters.\bigg
which makes it better looking! Thank's!!!